Bulletin of the Chemical Society of Japan p. 1781 - 1784 (1999)
Update date:2022-07-29
Topics:
Oyaizu, Kenichi
Haryono, Agus
Nishimura, Yukio
Yamamoto, Kimihisa
Tsuchida, Eishun
The crystal structure of a μ-oxo heterometallic porphyrin [(pip)(tpp)Cr(III)[OFe(III)[(tpp)] (pip = piperidine) not only confirmed the proposed oxidation state of chromium and iron atoms, but also revealed a unique coordination environment around chromium(III), which is substantially protruded from the porphyrin plane.
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