Tetrahedron Letters p. 2111 - 2114 (1993)
Update date:2022-08-02
Topics:
Brondani, Dalci J.
Corriu, Roben J. P.
El Ayoubi, Sabar
Moreau, Joel J. E.
Man, Michel Wong Chi
The THF solutions of (triethoxysilyl)methyl magnesium chloride are stable at low temperatures. At 20°C, the Grignard reagent underwent intermolecular condensation, providing a simple synthesis of cyclic carbosilanes derivatives. The cross-coupling reaction with organic halides also afforded a facile route to a variety of trifunctional organosilicon compounds.
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