Journal of Organometallic Chemistry p. 59 - 66 (1996)
Update date:2022-08-04
Topics:
Delpon-Lacaze
De Battisti
Couret
The dimesitylneopentylsilene Mes2Si=CH-CH2tBu 1 is obtained in almost quantitative yield by reaction of tert-butyllithium with dimesitylvinylfluorosilane 4; 1 is certainly one of the most easily available stable silenes. In spite of its stability, 1 presents a high reactivity in the field of classical chemistry of organometallic alkenes such as addition or cycloaddition reactions and, in some cases, an original behaviour of ene-reagent (towards benzaldehyde) and both ene- and enophilic-reagent (towards acetophenone).
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