Scholarly article on tert-Butyl-[1-tert-butyl-4-[3,3-dimethyl-but-(E)-ylidene]-3,3-bis-(2,4,6-trimethyl-phenyl)-[1,3]azasiletidin-(2E)-ylidene]-amine 179008-20-9 from Journal of Organometallic Chemistry p. 59 - 66

DOI: 10.1016/0022-328X(95)06036-V

Source and publish data:

Journal of Organometallic Chemistry p. 59 - 66 (1996)

Update date:2022-08-04

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Authors:

Delpon-Lacaze

De Battisti

Couret Couret

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Article abstract of DOI:10.1016/0022-328X(95)06036-V

The dimesitylneopentylsilene Mes₂Si=CH-CH₂^tBu 1 is obtained in almost quantitative yield by reaction of tert-butyllithium with dimesitylvinylfluorosilane 4; 1 is certainly one of the most easily available stable silenes. In spite of its stability, 1 presents a high reactivity in the field of classical chemistry of organometallic alkenes such as addition or cycloaddition reactions and, in some cases, an original behaviour of ene-reagent (towards benzaldehyde) and both ene- and enophilic-reagent (towards acetophenone).

Full text of DOI:10.1016/0022-328X(95)06036-V

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DOI: 10.1016/0022-328X(95)06036-V