Journal of Organometallic Chemistry p. C5 - C8 (1983)
Update date:2022-08-03
Topics:
Pratt, Sandra L.
Faltymek, Robert A.
Thermal and photochemical activation of Ph3SiMn(CO)5 leads to different catalyst systems, both of which promote the addition of organosilicon hydrides to terminal alkenes.In the thermal case, major catalytic activity is due to triphenylsilyl radicals generated from Si-Mn bond homolysis.Upon photolysis, however, there is no evidence of Si-Mn homolysis during catalyst activation.These studies represent the first well-defined example of disparate behavior upon photochemical vs. thermal activation of the same catalyst precursor.
View MoreChangzhou LanXu Chemical Co.,ltd.(expird)
Contact:86-0519-86330911,13656129734,15261186386
Address:Room 524, Depart.Chemical, Changzhou Science and Eductaion town, Jiangsu, China;Factory: Haian Fine Chemical Industry Park,Nantong,Jiangsu,China
Ningbo Hi-tech Zone Nice-Synth Chemical Industry Ltd.
Contact:+86-(574)-81110986
Address:No. 1210, Building 3, Wante Business Centre, Hi-tech Zone, Ningbo
Penglai Qianwei Chemical Co., Ltd.
Contact:86-535-3357802
Address:Shahelu (north), Penglai, Shandong, China
website:http://www.joyochem.com
Contact:0531-82687558, 0531-82687326
Address:Factory Building 11, Jinan Comprehensive free trade zone, Shandong, China
Shandong Hongxiang Zinc Co., Ltd
Contact:086-0311-66187879
Address:DaWang developing zone
Doi:10.1016/j.bmcl.2011.12.144
(2012)Doi:10.1039/jr9650006777
(1965)Doi:10.1021/jo00924a020
(1974)Doi:10.1021/jo00014a007
(1991)Doi:10.1002/ardp.19412790604
(1941)Doi:10.1021/om020807v
(2003)