Journal of the Chemical Society. Perkin transactions I p. 1261 - 1268 (1996)
Update date:2022-08-02
Topics:
Miyashita, Kazuyuki
Kondoh, Katsunori
Tsuchiya, Katsutoshi
Miyabe, Hideto
Imanishi, Takeshi
Thermolysis of 2-(N-acylamino)benzyl methyl ethers, in the presence of an acid catalyst and triphenylphosphine, or 2-(N-acylamino)benzylphosphonium salts is found to serve as a novel method for indole formation, in particular for the synthesis of 2-trifluoromethylindoles. The reaction of the benzyl methyl ethers is suggested to involve a phosphonium intermediate, which thermally decomposes to the indoles.
View MoreZhengzhou Institute of Chiral Pharmer Research Co., Ltd.
Contact:86-371-55219111
Address:15 Floor, 2 Building, Central China Technovalley, Zhongyuan West Road
Shanghai Rainbow Chemistry Co., Ltd.
Contact:+86-21-64968086-5815/5812
Address:3rd floor, Building 7, 251 Faladi Road, Zhangjiang Hi-Tech Park, Pudong District, Shanghai, P.R. China
Chengdu King-tiger Pharm-chem. Tech. Co., Ltd
Contact:028-85317716
Address:Tianfu Life Science Park, No. 88 South Keyuan Road, Gaoxin District, Chengdu City, Sichuan Province, PRC.
SICHUAN TONGSHENG AMINOACID CO.LTD
website:http://www.aminoacid.cc
Contact:86-838-2274206/2850606
Address:Room 1-11-1,No.19 of North TianShan Road,Deyang,Sichuan China
Contact:+91 - 22 - 26355700
Address:17, Lotus Business Park, Andheri West
Doi:10.1016/0960-894X(96)00426-X
(1996)Doi:10.1016/0040-4039(96)00809-X
(1996)Doi:10.1002/anie.200351954
(2003)Doi:10.1021/jo00838a022
(1969)Doi:10.1080/10426509708545604
(1997)Doi:10.1039/c9dt04870g
(2020)
