Journal of the Chemical Society. Perkin transactions I p. 1261 - 1268 (1996)
Update date:2022-08-02
Topics:
Miyashita, Kazuyuki
Kondoh, Katsunori
Tsuchiya, Katsutoshi
Miyabe, Hideto
Imanishi, Takeshi
Thermolysis of 2-(N-acylamino)benzyl methyl ethers, in the presence of an acid catalyst and triphenylphosphine, or 2-(N-acylamino)benzylphosphonium salts is found to serve as a novel method for indole formation, in particular for the synthesis of 2-trifluoromethylindoles. The reaction of the benzyl methyl ethers is suggested to involve a phosphonium intermediate, which thermally decomposes to the indoles.
View MoreGeen Chemical Technology Co., Ltd
Contact:86-769-21660847
Address:1408, Yingfeng Commercial Center, Nancheng District
website:http://www.antaibio.com
Contact:0086-21-65663057
Address:Room 2108, Building 2，No. 489 Zhengli Road，200433
ChangZhou XiaQing Chemical Co., Ltd.
Contact:+86-519-88721665
Address:3# Hengluo Road, Henglin Town, Changzhou City, Jiangsu Province，China
Contact:+86-10-67147360/67107388
Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
Angelisun(Chongqing) Pharmaceutical Co., LTD.
Contact:+86-23-68030926-816
Address:D1-7 Tech & Entrepreneurs Park, Kecheng Road, Erlang Hi-Tech Areas, Chongqing, China
Doi:10.1016/0960-894X(96)00426-X
(1996)Doi:10.1016/0040-4039(96)00809-X
(1996)Doi:10.1002/anie.200351954
(2003)Doi:10.1021/jo00838a022
(1969)Doi:10.1080/10426509708545604
(1997)Doi:10.1039/c9dt04870g
(2020)
