A directed stereoselective aldol reaction: Simple synthesis of enantiopure δ-hydroxy-β-enamino ketones by condensation of homochiral β-enamino ketones with aldehydes and ketones

DOI: 10.1016/0957-4166(96)00253-4

Source and publish data:

Tetrahedron Asymmetry p. 2099 - 2112 (1996)

Update date:2022-08-03

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Authors:

Cimarelli, Cristina

Palmieri, Gianni

Camalli, Mercedes

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Article abstract of DOI:10.1016/0957-4166(96)00253-4

A simple synthesis of enantiopure anti-δ-hydroxy-β-enamino ketones 3 by condensation of homochiral lithium dianions derived from β-enamino ketones 1'' with aldehydes and ketones is reported. The mechanism for the directed enantioselective aldol reaction w

Full text of DOI:10.1016/0957-4166(96)00253-4

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