A bis(cyclopalladated) tetranuclear derivative of methyl ferrocenyl ketone azine: [{Pd[(η5-C5H5)Fe(η5-C 5H3)CMe=N]Cl(PPh3)}2]

DOI: 10.1039/DT9960003195

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3195 - 3200 (1996)

Update date:2022-07-29

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Authors:

Bosque, Ramon

Lopez, Concepcion

Sales, Joaquim

Solans, Xavier

Silver, Jack

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Article abstract of DOI:10.1039/DT9960003195

The bis(cyclopalladated) tetranuclear compound [{Pd[η⁵-C₅H₅)Fe(η⁵-C ₅H₃)CMe=N]Cl(PPh₃)}₂] has been prepared and characterized. Proton and ³¹P NMR spectra reveal the presence of four diastereomers in solution. The crystal structure of the meso form has been determined by X-ray crystallography. This confirms the existence of two five-membered palladacycles with a σ(Pd-C_{sp2,ferrocene}) bond. Electrochemical studies, based on cyclic voltammetry, and Moessbauer spectra are also reported.

Full text of DOI:10.1039/DT9960003195

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