Synthesis and characterization of new metal, chloride complexes derived from 1-(benzotriazole-1-carbonylmethyl)-4-phenyl-3-thiosemicarbazide

Article abstract of DOI:10.1080/00945719608005135

The reaction of 1-(benzotriazole-1-carbonylmethyl)-4-phenyl-3-thiosemicarbazide (BPTS) with metal chlorides give three types of complexes having the compositions (1) [MLH₂]Cl₂, (2) [ML]H₂O, (3) M(LH)₂ [LH₂ = BPTS, M = Cu(II) , Co(II) , Ni(II) and Cd(II)]. Elemental analyses, IR spectral and TGA studies have been used to elucidate their stucture. The IR spectral data show that the heterocyclic thiosemicarbazide behaves as neutral, mononegative or binegative ligand and coordinates in a bidentate, tridentate or bridging tetradentate manner.

Full text of DOI:10.1080/00945719608005135

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Synthesis and Reactivity in
Inorganic and Metal-Organic
Chemistry
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Synthesis and Characterization
of New Metal Chloride
Complexes Derived from
1-(Benzotriazole-1-
carbonylmethyl)-4-phenyl-3-
thiosemicarbazide
Xu Pengfei a , Xu Zhuguo a , Liu Suyan b & Wu Shaozu
c
a Department of Chemistry , Lanzhou University ,
Lanzhou, 730000, P. R. China
b Department of Chemistry , Lanzhou Medical
College , Lanzhou, 730000, P. R. China
c Department of Science Research , Lanzhou
University , Beijing, 100088, P. R. China
d Department of Science Research , Central
Research Institute of Building and Construction of M.
M. I. , Beijing, 100088, P. R. China
Published online: 21 Aug 2006.
To cite this article: Xu Pengfei , Xu Zhuguo , Liu Suyan & Wu Shaozu (1996)
Synthesis and Characterization of New Metal Chloride Complexes Derived from
1-(Benzotriazole-1-carbonylmethyl)-4-phenyl-3-thiosemicarbazide, Synthesis
and Reactivity in Inorganic and Metal-Organic Chemistry, 26:8, 1437-1444, DOI:
10.1080/00945719608005135
To link to this article: http://dx.doi.org/10.1080/00945719608005135

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