Estimating the effective steric impact of PtBu2Me, PiPr3, and PCy3

DOI: 10.1021/om960380q

Source and publish data:

Organometallics p. 4900 - 4903 (1996)

Update date:2022-08-05

Topics:

Authors:

Li, Chunbang

Ogasawara, Masamichi

Nolan, Steven P.

Caulton, Kenneth G.

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Article abstract of DOI:10.1021/om960380q

Enthalpies of reaction of Ru(CO)₂L₂ (L = PⁱPr₃, P^tBu₂Me, and PCy₃) with MeNC, PhC≡CPh (both addition reactions) and PhCC-H (C-H oxidative addition) in toluene are exothermic in t

Full text of DOI:10.1021/om960380q

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