Exploitation of highly functionalised epoxides derived from asymmetrized tris(hydroxymethyl)methane (THYM*) in the synthesis of a fragment of lasalocide A and other related polyether ionofore antibiotics

DOI: 10.1016/0040-4020(96)00751-X

Source and publish data:

Tetrahedron p. 12631 - 12642 (1996)

Update date:2022-09-26

Topics:

Authors:

Guanti, Giuseppe

Narisano, Enrica

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(96)00751-X

A fragment for the total convergent synthesis of some polyether ionophore antibiotics (lasalocide A, isolasalocide A, lysocellin) has been obtained through 'higher order' vinyl cuprate ring opening of functionalised epoxides derived from THYM*.

Full text of DOI:10.1016/0040-4020(96)00751-X

Products guided by the article

Product name:(2S,3S,4S)-2-Benzyloxymethoxymethyl-1-(4-methoxy-benzyloxymethoxy)-4-methyl-hex-5-en-3-ol

Cas No:183017-08-5

R&D Labs maybe for 183017-08-5

C-LAB Chemievermittlung GmbH

Contact:+49-9398-993127

Address:Untertorstr. 27
Changzhou LanXu Chemical Co.,ltd.(expird)

Contact:86-0519-86330911,13656129734,15261186386

Address:Room 524, Depart.Chemical, Changzhou Science and Eductaion town, Jiangsu, China;Factory: Haian Fine Chemical Industry Park,Nantong,Jiangsu,China
Lanzhou huibang biological chemical technology Co., LTD

Contact:0931-7843964

Address:NO.2011,Yannan Road,Chengguan,
Shanghai Kefu Chemical Co.,Ltd.

Contact:+86-21-34616196

Address:Room601-602, Xuhui Business Building, No.168, Yude Road, Shanghai
Puyang Huicheng Electronic Material Co., Ltd

website:http://huichengchem.weba.testwebsite.cn/index_en.html

Contact:+86-393-8910800

Address:West Section Shengli Road, Puyang457000, China

Relevant to this article

Asymmetric construction of benzylic quaternary carbons by lipase-mediated enantioselective transesterification of prochiral α,α-disubstituted 1,3-propanediols

Doi:10.1016/S0957-4166(96)00500-9
(1997)
Doi:10.1016/S0040-4039(00)91037-2
(1975)
Doi:10.1021/jo50017a023
(1953)
Palladium-Catalyzed Defluorinative Alkylation of gem-Difluorocyclopropanes: Switching Regioselectivity via Simple Hydrazones

Doi:10.1002/anie.202102240
(2021)
Hypervalent (tert-butylperoxy)iodanes generate iodine-centered radicals at room temperature in solution: Oxidation and deprotection of benzyl and allyl ethers, and evidence for generation of α-oxy carbon radicals

Doi:10.1021/ja9610287
(1996)
Doi:10.1016/S0040-4039(01)98932-4
(1968)

Article Doi