Exploitation of highly functionalised epoxides derived from asymmetrized tris(hydroxymethyl)methane (THYM*) in the synthesis of a fragment of lasalocide A and other related polyether ionofore antibiotics

DOI: 10.1016/0040-4020(96)00751-X

Source and publish data:

Tetrahedron p. 12631 - 12642 (1996)

Update date:2022-09-26

Topics:

Authors:

Guanti, Giuseppe

Narisano, Enrica

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(96)00751-X

A fragment for the total convergent synthesis of some polyether ionophore antibiotics (lasalocide A, isolasalocide A, lysocellin) has been obtained through 'higher order' vinyl cuprate ring opening of functionalised epoxides derived from THYM*.

Full text of DOI:10.1016/0040-4020(96)00751-X

Products guided by the article

Product name:(2S,3S,4S)-2-Benzyloxymethoxymethyl-1-(4-methoxy-benzyloxymethoxy)-4-methyl-hex-5-en-3-ol

Cas No:183017-08-5

R&D Labs maybe for 183017-08-5

MTT Pharma & Bio-technology Co.,Ltd(expird)

Contact:+86-21-58407925

Address:Room2019, Building C, Tomson Center, No.158, Zhang Yang Road, Shanghai, China
Lanling Hongchuang Flame Retardant Co., Ltd.

Contact:+86-531-68858132

Address:East Huafeichang Road, Cangshan County, Linyi, Shandong, China (Mainland)
Hebei DaPeng Pharm & Chem Co., Ltd.

Contact:86-317-7298678,0576-88861898 88861908

Address:West Songmen Village, East Songmen Town, Wuqiao, Cangzhou, Hebei ,China
Zibo Jujin Chemical Industry Co., Ltd.（Dongming Jujin Chemical Industry Co., Ltd. ）

Contact:+86-533-2975022

Address:No.99 Shanquan Road, Zhangdian District
JIANGSU GRAND XINYI PHARMACEUTICAL CO.,LTD

website:http://www.xypharm.com/

Contact:+86-515-84383317

Address:Chenli Road,Costal Chemical Area Binhai,Yancheng, Jiangsu,China

Relevant to this article

Asymmetric construction of benzylic quaternary carbons by lipase-mediated enantioselective transesterification of prochiral α,α-disubstituted 1,3-propanediols

Doi:10.1016/S0957-4166(96)00500-9
(1997)
Doi:10.1016/S0040-4039(00)91037-2
(1975)
Doi:10.1021/jo50017a023
(1953)
Palladium-Catalyzed Defluorinative Alkylation of gem-Difluorocyclopropanes: Switching Regioselectivity via Simple Hydrazones

Doi:10.1002/anie.202102240
(2021)
Hypervalent (tert-butylperoxy)iodanes generate iodine-centered radicals at room temperature in solution: Oxidation and deprotection of benzyl and allyl ethers, and evidence for generation of α-oxy carbon radicals

Doi:10.1021/ja9610287
(1996)
Doi:10.1016/S0040-4039(01)98932-4
(1968)

Article Doi