Welcome to LookChem.com Sign In|Join Free

Article Doi

Role of bifunctional N/S bridging in the association of metals; syntheses and structures of heterobimetallic [(Ph3P)2CuL2Li(thf)2]·thf and tetrameric [{CuL(PPh3)}4] (L = 1,3-benzoxazoline-2-thionate, thf = tetrahydrofuran)

DOI: 10.1039/DT9960003793

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3793 - 3797 (1996)

Update date:2022-07-29

Topics:

Authors:

Beswick, Michael A.Beswick, Michael A.

Brasse, ClaudiaBrasse, Claudia

Halcrow, Malcolm A.Halcrow, Malcolm A.

Raithby, Paul R.Raithby, Paul R.

Russell, Christopher A.Russell, Christopher A.

Steiner, AlexanderSteiner, Alexander

Snaith, RonaldSnaith, Ronald

Wright, Dominic S.Wright, Dominic S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9960003793

Nucleophilic substitution of the cp (η-C5H5) ligand of [Cu(Cp)(PPh3)] with LiL (L = 1,3-benzoxazoline-2-thionate) gave the heterobimetallic complex [(Ph3P)2CuL2Li(thf)2]·thf 1 (thf = tetrahydrofuran), the ligand-transfer reaction of which with CuCl2 generated the tetrameric cage complex [{CuL(PPh3)}4] 2. The crystal structures of these complexes revealed that the association of the metal centres occurs by a variety of ligand co-ordination modes (μ-S, N; N, μ-S; μ3-S). Electrochemical measurements have been used to probe the nature of the species present in solution.

View More

Products guided by the article

Product name:[Cu(P(C6H5)3)2(C7H4NOS)2Li(OC4H8)2]*OC4H8

Cas No:183323-85-5

183323-85-5

R&D Labs maybe for 183323-85-5

Relevant to this article

Hot Product