Journal of the Chemical Society, Dalton Transactions p. 3793 - 3797 (1996)
Update date:2022-07-29
Topics:
Beswick, Michael A.
Brasse, Claudia
Halcrow, Malcolm A.
Raithby, Paul R.
Russell, Christopher A.
Steiner, Alexander
Snaith, Ronald
Wright, Dominic S.
Nucleophilic substitution of the cp (η-C5H5) ligand of [Cu(Cp)(PPh3)] with LiL (L = 1,3-benzoxazoline-2-thionate) gave the heterobimetallic complex [(Ph3P)2CuL2Li(thf)2]·thf 1 (thf = tetrahydrofuran), the ligand-transfer reaction of which with CuCl2 generated the tetrameric cage complex [{CuL(PPh3)}4] 2. The crystal structures of these complexes revealed that the association of the metal centres occurs by a variety of ligand co-ordination modes (μ-S, N; N, μ-S; μ3-S). Electrochemical measurements have been used to probe the nature of the species present in solution.
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