Role of bifunctional N/S bridging in the association of metals; syntheses and structures of heterobimetallic [(Ph3P)2CuL2Li(thf)2]·thf and tetrameric [{CuL(PPh3)}4] (L = 1,3-benzoxazoline-2-thionate, thf = tetrahydrofuran)

DOI: 10.1039/DT9960003793

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3793 - 3797 (1996)

Update date:2022-07-29

Topics:

Authors:

Beswick, Michael A.

Brasse, Claudia

Halcrow, Malcolm A.

Raithby, Paul R.

Russell, Christopher A.

Steiner, Alexander

Snaith, Ronald

Wright, Dominic S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9960003793

Nucleophilic substitution of the cp (η-C₅H₅) ligand of [Cu(Cp)(PPh₃)] with LiL (L = 1,3-benzoxazoline-2-thionate) gave the heterobimetallic complex [(Ph₃P)₂CuL₂Li(thf)₂]·thf 1 (thf = tetrahydrofuran), the ligand-transfer reaction of which with CuCl₂ generated the tetrameric cage complex [{CuL(PPh₃)}₄] 2. The crystal structures of these complexes revealed that the association of the metal centres occurs by a variety of ligand co-ordination modes (μ-S, N; N, μ-S; μ₃-S). Electrochemical measurements have been used to probe the nature of the species present in solution.

Full text of DOI:10.1039/DT9960003793

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Cu(P(C₆H₅)3)2(C₇H₄NOS)2Li(OC₄H₈)2]*OC₄H₈

Cas No:183323-85-5

R&D Labs maybe for 183323-85-5

CHENGDU CHENLV HERB CO.,LTD

Contact:+86-28-88523492

Address:714rooms of Time Square, Pujiang County
PINGYUAN SIHUAN PHARMACEUTICAL CO., LTD

Contact:+86-531-55696072

Address:#2766,yinxiu Road, Economic Development Zone, Pingyuan Country, Shandong Province, China.
Shanghai Zhihua ChemTech Co., Ltd.

Contact:+86-13774313779

Address:Room 817 Suite B 3333 Shenjiang Road
SHANGHAI ARCADIA BIOTECHNOLOGY LTD.

Contact:+86-21-61353236

Address:SUITE 901, BUILDING WENSLI, 1378 LU JIA BANG RD, SHANGAHI 200011, P.R.CHINA
Shanghai Profirst Co., Ltd.

Contact:+86-21-38122007

Address:2, Lane 1123, Kangqiao Road, Pudong New Area, Shanghai

Relevant to this article

Isolation and characterization of the acyl complexes trans- (R=n-Bu or s-Bu) and their relevance to the hydroformylation of linear butenes catalyzed by platinum/tin/triphenylphosphine catalytic systems. Molecular structure of cis-

Doi:10.1016/0022-328X(94)88056-5
(1994)
Doi:10.1002/jlcr.2590070402
(1971)
Compounds containing 3-metallated pyrrole

Doi:10.1016/S0022-328X(96)06465-0
(1996)
Stereoselective synthesis and biological evaluation of anisomycin and 2- substituted analogues

Doi:10.1055/s-1999-3661
(1999)
Doi:10.1021/ja00902a024
(1963)
First total syntheses of cytotoxic substances russuphelins A-C

Doi:10.1080/00397919708004811
(1997)

Article Doi