First synthesis and structure of optically pure Te-chiral-alkoxytelluranes

DOI: 10.1016/0957-4166(96)00365-5

Source and publish data:

Tetrahedron Asymmetry p. 2797 - 2800 (1996)

Update date:2022-08-02

Topics:

Authors:

Takahashi, Tamiko

Zhang, Jian

Kurose, Noriyuki

Takahashi, Shigemasa

Koizumi, Toru

Shiro, Motoo

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Article abstract of DOI:10.1016/0957-4166(96)00365-5

The first synthesis and isolation of optically pure Te-chiral-alkoxytelluranes 1 and 8 have been developed using the 2-exo-hydroxy-10-bornyl group as a chiral ligand. A distorted trigonal bipyramidal (TBP) structure of 1i with R configuration was confirmed by the X-ray analysis.

Full text of DOI:10.1016/0957-4166(96)00365-5

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Product name:(1S,5R,7R)-3-Iodo-10,10-dimethyl-3-phenyl-4-oxa-3λ⁴-tellura-tricyclo[5.2.1.0^1,5]decane

Cas No:183446-17-5

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