
Tetrahedron Letters p. 7065 - 7068 (1996)
Update date:2022-08-02
Topics:
Ogino, Toshio
Wada, Fumio
Murayama, Takayoshi
Aoki, Sansei
Ohshima, Kazuko
The photochemistry of newly synthesized 8,9-diphenyltricyclo[5.2.1.02,6]deca-4,8-dien-3-one (1) has been explored. A novel [1, 3] sigmatropic rearrangement via a singlet excited state was observed as well as a [2 + 2] intramolecular cycloaddition via a triplet excited state. The formation of an intramolecular singlet exciplex was indicated by emission spectra.
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Doi:10.1002/hlca.19960790708
(1996)Doi:10.1021/om9603981
(1996)Doi:10.1016/0040-4020(96)00867-8
(1996)Doi:10.1016/0957-4166(96)00413-2
(1996)Doi:10.1016/j.ejmech.2011.04.042
(2011)Doi:10.1016/0040-4039(96)01879-5
(1996)