Journal of Physical Chemistry p. 19636 - 19641 (1996)
Update date:2022-08-03
Topics:
Vanoppen
Grim
Ruecker
De Feyter
Moessner
Valiyaveettil
Muellen
De Schryver
Scanning tunneling microscopy (STM) was used to study physisorbed monolayers of 5-octadecyloxyisophthalic acid (C18ISA) and 5-[ω-(4′-dodecyloxy-4-azobenzeneoxy)dodecyloxy]isophthalic acid (C12(AZO)C12ISA) at a liquid/graphite interface. The acquired STM images exhibit the molecular packing of the monolayers with submolecular resolution. Monolayers formed by codeposition of solvent molecules and C18ISA or C12(AZO)C12-ISA molecules are found when 1-octanol and 1-undecanol are used as a solvent. The cis and trans isomers of C12(AZO)C12ISA, the reagent and reaction product of a reversible photoinduced reaction, are simultaneously present and are both structurally identified at the liquid/graphite interface.
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