Chemistry Letters p. 1123 - 1124 (1996)
Update date:2022-09-26
Topics:
Mukaiyama, Teruaki
Takeuchi, Kazuya
Higuchi, Satoshi
Uchiro, Hiromi
A new efficient method for the catalytic stereoselective synthesis of various α-L-fucosides by using an easily available and stable glycosyl donor, 2,3,4-tri-O-benzyl-L-fucopyranosyl methoxyacetate, is established. Also, trimethylsilyl trifluoroacetate and lithium perchlorate are found to be effective additives in the synthesis of Fucα1-3GlcNAc and Fucα1-4GlcNAc linkages.
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