Journal of Organometallic Chemistry p. 145 - 154 (1997)
Update date:2022-07-29
Topics:
Chaloner, Penny A.
Davies, Sian E.
Hitchcock, Peter B.
Reaction of [Pt(C2H4)(PPh3)2] with propenoate or 2-methylpropenoate esters gave the complexes [Pt(propenoate)(PPh3)2] in good yield. These have been characterised by 1H, 13C, 31P and 195Pt NMR spectroscopy. The complex of benzyl propenoate has been characterised in a diffraction study. Reaction of the complexes produced with tricyclohexylphosphine, PCy3, gave [Pt(propenoate)(PCy3)(PPh3)]. The propenoate complexes were shown to be more stable than those of the 2-methylpropenoates.
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