Journal of the Chemical Society, Dalton Transactions p. 4331 - 4336 (1996)
Update date:2022-08-04
Topics:
Zurita, Dacil
Scheer, Corinne
Pierre, Jean-Louis
Saint-Aman, Eric
The complexation of copper(II) (from the perchlorate) by two tripodal ligands H2L bearing one pyridine and two phenolic arms has been studied in co-ordinating solvents. One of the ligands bears a MeS group at the para position of one of the phenolic moieties. In the presence of triethylamine, only brown dimeric neutral complexes [(CuL)2] have been obtained. In the absence of base, green [Cu(HL)]+ complexes were identified, in which one of the phenolic ligands remains protonated. The brown and the green complexes are reversibly interconverted upon addition of acid or base. Some evidence is given supporting the hypothesis of protonation of the axial tyrosine ligand in the form of galactose oxidase which has been isolated with an exogenous ligand bound to Cu. Electrochemical studies have been performed for the free pro-ligands and for the copper complexes.
View MoreSuzhou Wedo Chemicals Co., Ltd.
Contact:86 512 58100425
Address:Zonger Road, DongSha Industry Park , Zhangjiagang, Jiangsu, China
FOSHAN NANHAI ZHONGNAN PHARMACEUTICAL FACTORY
Contact:0086-0757-85609331
Address:XIAHENGTIAN INDUSTRIAL ZONE,SHAYONG VILLAGE,LISHUI TOWN
Contact:86-532-68629711 13780605697
Address:NO 220 YANAN 3 ROAD,(POST ADMINISTRATION BUILDING),QINGDAO,CHINA
Jewim Pharmaceutical (Shandong) Co., Ltd
Contact:+8615621883869
Address:山东省泰安市高新技术产业开发区配天门大街西首
Jingzhou TianHe Sci&Tech Chemical Co., Ltd.
Contact:86-716-8331612
Address:Jiangjin Road, #18, High-grade technology industries development district, Jingzhou city, Hubei province
Doi:10.1016/0040-4020(95)00324-2
(1995)Doi:10.1039/DT9950002831
(1995)Doi:10.1002/anie.201702409
(2017)Doi:10.1007/BF00915656
()Doi:10.1002/jhet.5570320420
(1995)Doi:10.1016/j.poly.2012.06.025
(2012)
