Journal of Organometallic Chemistry p. 271 - 273 (1996)
Update date:2022-09-26
Topics:
Cowley, Alan H.
Decken, Andreas
Olazabal, Claudia A.
The first examples of digallium compounds that feature both organo and halo substituents, [Li(THF)4][Ar′(Cl)GaGaCl3] (1) and Ar′(Cl)GaGa(Cl)Ar′ (2), have been prepared by reaction of Ga2Cl4·2 dioxane with LiAr′ (Ar′= 2,4,6-1Bu3C6H2). The Ga2Cl2 skeleton of 2 is planar with a dihedral angle of 180°.
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