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Hybrid inorganic-organometallic compounds with gallium-gallium bonds

DOI: 10.1016/S0022-328X(96)06382-6

Source and publish data:

Journal of Organometallic Chemistry p. 271 - 273 (1996)

Update date:2022-09-26

Topics:

Authors:

Cowley, Alan H.Cowley, Alan H.

Decken, AndreasDecken, Andreas

Olazabal, Claudia A.Olazabal, Claudia A.

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Article abstract of DOI:10.1016/S0022-328X(96)06382-6

The first examples of digallium compounds that feature both organo and halo substituents, [Li(THF)4][Ar′(Cl)GaGaCl3] (1) and Ar′(Cl)GaGa(Cl)Ar′ (2), have been prepared by reaction of Ga2Cl4·2 dioxane with LiAr′ (Ar′= 2,4,6-1Bu3C6H2). The Ga2Cl2 skeleton of 2 is planar with a dihedral angle of 180°.

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Full text of DOI:10.1016/S0022-328X(96)06382-6

Products guided by the article

Product name:[Li(THF)4]Ga2Cl4(2,4,6-(t-Bu)3C6H2)

Cas No:186599-93-9

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