
Journal of Organometallic Chemistry p. 159 - 168 (1990)
Update date:2022-08-03
Topics:
Cerveau, G.
Chuit, C.
Corriu, R. J. P.
Nayyar, N. K.
Reye, C.
The reactions of hydro, organyl and halosilatranes with nucleophiles have been studied.Substitution involving cleavage of equatorial Si-O bonds is always observed.Silitranes exhibit reactivity quite different from that of analogous trialkoxysilanes or anionic pentacoordinate silicon compounds.
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