Pentacoordinate silicon compounds. Reactions of silatranes with nucleophiles

DOI: 10.1016/0022-328X(90)85408-Q

Source and publish data:

Journal of Organometallic Chemistry p. 159 - 168 (1990)

Update date:2022-08-03

Topics:

Authors:

Cerveau, G.

Chuit, C.

Corriu, R. J. P.

Nayyar, N. K.

Reye, C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(90)85408-Q

The reactions of hydro, organyl and halosilatranes with nucleophiles have been studied.Substitution involving cleavage of equatorial Si-O bonds is always observed.Silitranes exhibit reactivity quite different from that of analogous trialkoxysilanes or anionic pentacoordinate silicon compounds.

Full text of DOI:10.1016/0022-328X(90)85408-Q

Products guided by the article

Product name:benzyltri-1-butylsilane

Cas No:18663-12-2

R&D Labs maybe for 18663-12-2

Huangshi Shennong Chemical Technology Co., Ltd

Contact:+86-714-3072290

Address:Eastern industrial park , Tieshan district , Huangshi city ,Hubei province , China
Anqing World Chemical Co., Ltd.

Contact:+86-556-5800026

Address:Daguan Economic Development Zone of circular economy industrial park Anqing City Anhui province
Changyi Xinxing Technology Development Co., Ltd.

Contact:0086-510-86651065(Time Zone:8),86651656

Address:94 Yingbinxilu WestRoad, Huangtu Town, Jiangyin City, Jiangsu, China
Henan Blight Industry Co., Ltd

Contact:13203734935 371-8284635

Address:ZhengzhouHuayuan Road
Suzhou Lixin Pharmaceutical Co., Ltd.

Contact:86-512-88169812

Address:21 Tangxi Road, Suzhou New District, Suzhou 215151

Relevant to this article

Nitrous oxide mediated synthesis of monomeric hydroxoruthenium complexes. Reactivity of (DMPE)₂Ru(H)(OH) and the synthesis of a silica-bound ruthenium complex

Doi:10.1021/om980295d
(1998)
Enantioselective N-acetylation of N-desisopropylpropranolol by rat liver acetyltransferase

Doi:10.1248/bpb.21.1361
(1998)
Synthesis and characterization of dimeric bile acid ester derivatives

Doi:10.1002/prac.19973390135
(1997)
A novel synthetic approach to 2,2,2-trifluoroethylidene derivatives from ketones

Doi:10.1248/cpb.45.43
(1997)
Syntheses of New Phosphono Analogues of Pantetheine Derivatives

Doi:10.1002/hlca.19970800109
(1997)
Synthesis, in vitro anti-HIV activity, and biological stability of 5'- O-myristoyl analogue derivatives of 3'-fluoro-2',3'dideoxythymidine (FLT) as potential bifunctional prodrugs of FLT

Doi:10.1080/07328319808004216
(1998)

Article Doi