Pentacoordinate silicon compounds. Reactions of silatranes with nucleophiles

DOI: 10.1016/0022-328X(90)85408-Q

Source and publish data:

Journal of Organometallic Chemistry p. 159 - 168 (1990)

Update date:2022-08-03

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Authors:

Cerveau, G.

Chuit, C.

Corriu, R. J. P.

Nayyar, N. K.

Reye, C.

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Article abstract of DOI:10.1016/0022-328X(90)85408-Q

The reactions of hydro, organyl and halosilatranes with nucleophiles have been studied.Substitution involving cleavage of equatorial Si-O bonds is always observed.Silitranes exhibit reactivity quite different from that of analogous trialkoxysilanes or anionic pentacoordinate silicon compounds.

Full text of DOI:10.1016/0022-328X(90)85408-Q

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