A novel synthetic approach to 2,2,2-trifluoroethylidene derivatives from ketones

DOI: 10.1248/cpb.45.43

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 43 - 47 (1997)

Update date:2022-08-03

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Authors:

Kaneko, Satoru

Nakajima, Noriyuki

Katoh, Tadashi

Terashima, Shiro

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Article abstract of DOI:10.1248/cpb.45.43

An approach to 2,2,2-trifluoroethylidene derivatives from ketones was explored by employing the Corey-Winter's reductive elimination of 4- trifluoromethyl-1,3-dioxolane-2-thiones to 2,2,2-trifluoroethylidene derivatives as a key step. The 1,3-dioxolane-2-

Full text of DOI:10.1248/cpb.45.43

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