A stereoselective total synthesis of (±)-oppositol by a doubly diastereoselective intramolecular ester enolate alkylation

DOI: 10.1016/S0040-4039(96)02313-1

Source and publish data:

Tetrahedron Letters p. 415 - 416 (1997)

Update date:2022-08-03

Topics:

Authors:

Kim, Deukjoon

Kim, In Ho

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(96)02313-1

The brominated terpene (±)-oppositol (1) has been synthesized utilizing a novel doubly diastereodifferentialing 'folding and allylic strain-controlled' intramolecular ester enolate alkylation.

Full text of DOI:10.1016/S0040-4039(96)02313-1

Products guided by the article

Product name:6-Hydroxy-4-(2-hydroxy-ethyl)-3-{2-[2-(4-methoxy-benzyloxy)-ethyl]-[1,3]dioxolan-2-yl}-2-methyl-hexanoic acid ethyl ester

Cas No:186750-57-2

R&D Labs maybe for 186750-57-2

Hangzhou Ledun Technology Co.,Ltd.

Contact:86-571-18767088918

Address:No.6 street,XiaSha,Hangzhou,China.
X.T.Y Environ-Tech Co.,Ltd

Contact:+86-310-7092106

Address:Quzhou Modern & New Industrial Park, Handan, Hebei 057250, China
Changzhou Hopschain Chemical Co.,Ltd

website:http://www.hopschem.cn/products.html

Contact:86-519-85528066

Address:Room 710, Unit A, Xingbei Development Mansion, Tongjiang Road, Changzhou City,213000, China
Zhejiang Rongkai Chemical Technology Co.,Ltd.

Contact:+86-578-8185786

Address:Shangjiang Industrial Zone,Suichang
Nanjing Fayekong Chemcial Co.,Ltd(expird)

Contact:86-25-58813444

Address:Rm 1503, Unit 1, Building 5, Zijinnanyuan, Nanjing, Jiangsu, China

Relevant to this article

Doi:10.1021/ja01502a025
(1960)
Doi:10.1021/jo01256a067
(1969)
Doi:10.1039/C19670001179
(1967)
Synthesis and in vitro cytotoxicity of a series of 3-aminoflavones

Doi:10.1016/S0223-5234(97)84363-2
(1997)
Doi:10.1021/jo01356a015
(1957)
Some esters of N-(D-6 methyl 8 ergolin I ylmethyl)-carbamic acid

Doi:10.1135/cccc19771886
(1977)

Article Doi