A stereoselective total synthesis of (±)-oppositol by a doubly diastereoselective intramolecular ester enolate alkylation

DOI: 10.1016/S0040-4039(96)02313-1

Source and publish data:

Tetrahedron Letters p. 415 - 416 (1997)

Update date:2022-08-03

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Authors:

Kim, Deukjoon

Kim, In Ho

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Article abstract of DOI:10.1016/S0040-4039(96)02313-1

The brominated terpene (±)-oppositol (1) has been synthesized utilizing a novel doubly diastereodifferentialing 'folding and allylic strain-controlled' intramolecular ester enolate alkylation.

Full text of DOI:10.1016/S0040-4039(96)02313-1

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