Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 533 - 544 (1986)
Update date:2022-09-26
Topics:
Homer, John
Perry, Michael C.
An n.m.r. counterpart of the classical Job method for determining the stoicheiometry of molecular complexes by spectrophotometry is derived.It is applied to the fluoranil-hexamethylbenzene and acetonitrile-benzene systems, for which stoicheiometries consistent with those deduced classically are obtained, although for the latter system an additional complex is identified.The method is used to reveal the dependence of the measured stoicheiometry on the solution concentration of the interacting species.It is demonstrated that 1:1 and 1:2 complexes can be identified separately when they coexist, and that the equilibrium constant for the formation of the former can be measured readily.
View MoreShanghai KFSL Pharmaceutical Technology Co.,Ltd.
Contact:+86-21-39971718
Address:859 jiadingchengliu shanghai
JiangXi Hong Run Chemical Co., Ltd
Contact:+86-0791-88521351
Address:XingHuo industrial zone in YongXiu county
YingYing Pharmaceutical Co.,Ltd
Contact:86-18854126208
Address:55#, yingxiongshan road
Fusilin chemical science & technology co., ltd.
Contact:532-80698166/86057573, +86-400-669-7885
Address:School of Material Science & Engineering, Shandong Uinversity of Science & Technology, Huangdao Zone, Qindao, Shandong
SINO Industries Company Limited(expird)
Contact:86-29-85369724
Address:No.111, Jiefang Road, Xi’an, China
Doi:10.1002/asia.202001003
(2020)Doi:10.1039/a605337h
(1997)Doi:10.1016/S0040-4039(97)00141-X
(1997)Doi:10.1016/j.bmc.2012.01.009
(2012)Doi:10.1021/jo01119a012
(1955)Doi:10.1021/ic961190a
(1997)
