The tandem Pummerer-isomunchnone route to (±)-pumiliotoxin C

DOI: 10.1016/S0040-4039(97)00141-X

Source and publish data:

Tetrahedron Letters p. 1505 - 1508 (1997)

Update date:2022-09-26

Topics:

Authors:

Kuethe, Jeffrey T.

Padwa, Albert

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(97)00141-X

The Pummerer reaction of imidosulfoxides containing tethered π-bonds results in the formation of isomunchnone dipoles which readily undergo intramolecular dipolar cycloaddition to furnish 5-substituted α-pyridones. An application of the method to (±)-pumiliotoxin C was carried out.

Full text of DOI:10.1016/S0040-4039(97)00141-X

Products guided by the article

Product name:Acetic acid 1-benzyl-2-oxo-1,2,5,6,7,8-hexahydro-quinolin-3-yl ester

Cas No:188350-90-5

R&D Labs maybe for 188350-90-5

Shijiazhuang Frontierchem Co., Ltd.

Contact:+86-311-89271196

Address:4-4-202 No.15 Biandian Street,Shijiazhuang
Liaoyang Xinyou Chemical Products Co.,Ltd.

Contact:+86-419-5165433 13604191870

Address:Huishang Road6-1, Hongwei District, Liaoyang, Liaoning, China
Chongqing Shuangfeng Chemical Co.,Ltd

Contact:+86-23-49850156

Address:No.663,xuanhua Rd,yongchuan,chongqing,China
Jinan Finer Chemical Co., Ltd

website:https://www.finerchem.com

Contact:+86-531-88989536

Address:New Material Industrial Park, Jinan City, China
Suzhou Wedo Chemicals Co., Ltd.

Contact:86 512 58100425

Address:Zonger Road, DongSha Industry Park , Zhangjiagang, Jiangsu, China

Relevant to this article

Use of 1,2,3-Selenadiazoles in the synthesis of 1,1'- bis(diphenylselenophosphoryl)ferrocene

Doi:10.1007/s10593-012-1129-5
(2012)
An alkylated coumarin from Kayea assamica

Doi:10.1016/S0031-9422(96)00616-4
(1997)
Discovery of Aporphine Analogues as Potential Antiplatelet and Antioxidant Agents: Design, Synthesis, Structure–Activity Relationships, Biological Evaluations, and in silico Molecular Docking Studies

Doi:10.1002/cmdc.201800318
(2018)
Total synthesis of balanol, part 2. Completion of the synthesis and investigation of the structure and reactivity of two key heterocyclic intermediates

Doi:10.1016/S0040-4020(97)00167-1
(1997)
Organocatalytic aldol reaction of indole-3-carbaldehydes with ketones: Synthesis of chiral 3-substituted indoles

Doi:10.1016/j.tetlet.2013.06.056
(2013)
Enantioselective conjugate addition of 3-fluoro-oxindoles to vinyl sulfone: An organocatalytic access to chiral 3-fluoro-3-substituted oxindoles

Doi:10.1039/c3ob41267a
(2013)

Article Doi