The first total synthesis of calbistrin A, a microbial product possessing multiple bioactivities

DOI: 10.1016/S0040-4039(96)02377-5

Source and publish data:

Tetrahedron Letters p. 583 - 586 (1997)

Update date:2022-09-26

Topics:

Authors:

Tatsuta, Kuniaki

Itoh, Manabu

Hirama, Ryusuke

Araki, Nobuyuki

Kitagawa, Masayuki

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Article abstract of DOI:10.1016/S0040-4039(96)02377-5

The octahydronaphthopyranone moiety is synthesized from methyl α-D-mannopyranoside through the intramolecular Diels-Alder reaction, and the tetraenedicarboxylic acid moiety is from the enzymatically prepared anti-compound. Both moieties were coupled to accomplish the total synthesis of calbistrin A and to disclose its absolute structure.

Full text of DOI:10.1016/S0040-4039(96)02377-5

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