Tetrahedron Letters p. 583 - 586 (1997)
Update date:2022-09-26
Topics:
Tatsuta, Kuniaki
Itoh, Manabu
Hirama, Ryusuke
Araki, Nobuyuki
Kitagawa, Masayuki
The octahydronaphthopyranone moiety is synthesized from methyl α-D-mannopyranoside through the intramolecular Diels-Alder reaction, and the tetraenedicarboxylic acid moiety is from the enzymatically prepared anti-compound. Both moieties were coupled to accomplish the total synthesis of calbistrin A and to disclose its absolute structure.
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(1997)Doi:10.1021/jo9623494
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(1997)