A facile and efficient route to the bicyclo[3.2.1]octane system. Application to the enantioselective approach to cyclopentanoids

DOI: 10.1039/cc9960002743

Source and publish data:

Chemical Communications p. 2743 - 2744 (1996)

Update date:2022-08-04

Topics:

Authors:

Kosugi, Hiroshi

Sugiura, Junichiro

Kato, Michiharu

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Article abstract of DOI:10.1039/cc9960002743

The reaction of (4R,5R)-1-acetoxy-4-(1,2-epoxy-1-methyl-ethyl)-5-methylcyclohex-1-ene 8 with BF₃·Et₂O provides, in one chemical operation, (1R,4R,5R,7S)-7-acetoxy-4,6-dimethylbicyclo[3.2.1]octan-2-ones 9a,b which are then transformed

Full text of DOI:10.1039/cc9960002743

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