A facile and efficient route to the bicyclo[3.2.1]octane system. Application to the enantioselective approach to cyclopentanoids

DOI: 10.1039/cc9960002743

Source and publish data:

Chemical Communications p. 2743 - 2744 (1996)

Update date:2022-08-04

Topics:

Authors:

Kosugi, Hiroshi

Sugiura, Junichiro

Kato, Michiharu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/cc9960002743

The reaction of (4R,5R)-1-acetoxy-4-(1,2-epoxy-1-methyl-ethyl)-5-methylcyclohex-1-ene 8 with BF₃·Et₂O provides, in one chemical operation, (1R,4R,5R,7S)-7-acetoxy-4,6-dimethylbicyclo[3.2.1]octan-2-ones 9a,b which are then transformed

Full text of DOI:10.1039/cc9960002743

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Acetic acid (4R,5R)-4-isopropenyl-5-methyl-cyclohex-1-enyl ester

Cas No:187223-33-2

R&D Labs maybe for 187223-33-2

Jiangsu Haian Petro chemical Plant

Contact:+86-513-88902723

Address:99, Changjiang West Road, Haian County, Jiangsu
ALPHA PHARMACEUTICAL CO，LTD JIANGSU

Contact:+86-527-84829968,+86-527-84829998

Address:suqian city
Xinchang Yueding Chemical Co., Ltd.

Contact:86-571-56926323

Address:NO.90 BEIMENCHENGWAI CHENGGUAN TOWN XINCHANG
TIANJIN ZHONGXIN CHEMTECH CO.,LTD.

Contact:86-022-66880623

Address:FINANCIAL STREET WEST BLK 7, #308, NO.52 XINCHENG WEST ROAD, TEDA, TIANJIN, P.R.CHINA
Jintan City Mego Chemical Co., Ltd

Contact:+86-0519-82814387

Address:23# Dengguan Town, Jintan, Jiangsu Province, China

Relevant to this article

Aminorhenium carbon dioxide complexes: Formal oxidation of a carbon monoxide ligand with peroxy-acids or bromine/hydroxide

Doi:10.1016/j.jorganchem.2003.09.051
(2004)
Regioselective synthesis of photolabile P(1,2)- and P(4,5)-(o-nitrobenzyl) esters of myo-inositol 1,2,3,4,5,6-hexakisphosphate

Doi:10.1016/S0040-4039(96)02501-4
(1997)
Stereochemistry of the oxidation of gibberellin 20-alcohols, GA₁₅ and GA₄₄, to 20-aldehydes by gibberellin 20-oxidases

Doi:10.1039/a606158c
(1997)
Framework: Vs. side-chain amphidynamic behaviour in oligo-(ethylene oxide) functionalised covalent-organic frameworks

Doi:10.1039/c8cc04292f
(2018)
Total Synthesis of a Docosahexaenoic Acid Prostanoid Using an Intramolecular Organocatalytic Michael Reaction of a Formyl-Enal Derivative

Doi:10.1021/acs.orglett.0c02553
(2020)
Convenient synthesis of 2,2-disubstituted-2,3-dihydro-1,4-benzodioxins from 2-substituted-2-hydroxy-2,3-dihydro-1,4-benzodioxins

Doi:10.1016/S0040-4020(96)01140-4
(1997)

Article Doi