Construction of 8-Membered Ring Skeleton of Vinigrol via SmI2-Promoted Barbier Coupling

DOI: 10.1055/s-1997-748

Source and publish data:

Synlett p. 219 - 220 (1997)

Update date:2022-08-03

Topics:

Authors:

Kito Kito

Sakai Sakai

Shirahama

Miyashita

Matsuda Matsuda

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Article abstract of DOI:10.1055/s-1997-748

The 8-membered ring framework of vinigrol, a unique tricyclic diterpene isolated as a novel antihypertensive compound from a culture of Virgaria nigra, was efficiently synthesized employing an SmI₂-induced intramolecular Barbier coupling.

Full text of DOI:10.1055/s-1997-748

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