Tetrahedron Letters p. 1117 - 1120 (1997)
Update date:2022-08-03
Topics:
Xu, Yanping
Johnson, Carl R.
(1R,4S,6S)-4-Acetoxy-6-triisopropylsilyl prepared from cycloheptatriene utilizing an asymmetrization of the precursor diol with Candida antarctica lipase B/isopropenyl acetate, was converted to (1S,3R,4S,5S,6R,7R)-4,6,7-triacetoxy-5-benzyloxymethyl-4-acetoxymethyl-2,8 -dioxabicyclo[3.2.1]octane representing,the core of zaragozic acid by a strategy involving Rubottom oxidations and ozonolysis.
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(2012)Doi:10.1016/S0960-894X(97)00079-6
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(1997)
