Synthesis p. 156 - 158 (1997)
Update date:2022-08-02
Topics:
Kroutil, Wolfgang
Osprian, Ingrid
Mischitz, Martin
Faber, Kurt
The pheromone (S)-(-)-frontalin (1) was synthesized in five steps in 94percent ee via a chemoenzymatic route. In the key step, 2-methyl-2-(pent-4-enyl)oxirane [(±)-7a] was resolved employing lyophilized cells of Rhodococcus equi IFO 3730 (E = 39).
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Doi:10.1021/acs.joc.8b02738
(2019)Doi:10.1246/cl.1997.173
(1997)Doi:10.1080/00945719708000150
(1997)Doi:10.1039/a903476e
(1999)Doi:10.1021/ja01149a521
(1951)Doi:10.1021/jo01115a022
(1956)
