Synthesis, magneto-spectral and thermal studies of cobalt(II) and nickel(II) complexes of 4-[N-(4-dimethylaminobenzylidene)amino]antipyrine

Article abstract of DOI:10.1080/00945719708000150

Reactions of MX₂ (M = Co or Ni, X = Cl^-, Br^-, I^-, NO^-₃, NCS^-, or ClO^-₄) with 4-[N-(4-dimethylaminobenzylidene)-amino]antipyrine (DABAAP) yielded complexes of the type [M(DABAAP)₂X₂] or [M(DABAAP)₃](ClO₄)₂. The IR spectra of these complexes indicate that the ligand is a neutral bidentate ligand coordinating through the azomethine nitrogen and carbonyl oxygen. All the complexes are six-coordinated according the data of magnetic and electronic spectral measurements.

Full text of DOI:10.1080/00945719708000150

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Synthesis and Reactivity in
Inorganic and Metal-Organic
Chemistry
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Synthesis, Magneto-Spectral
and Thermal Studies of
Cobalt(II) and Nickel(II)
Complexes of 4-[N-(4-
Dimethylaminobenzylidene)
amino] Antipyrine
R. K. Agarwal a , Priyanka Garg a , Himanshu Agarwal
b & Sulekh Chandra b
a Department of Chemistry , Lajpat Rai Post-
Graduate College (Ch. Charan Singh University) ,
Sahibabad, 201005, Ghaziabad, India
b Department of Chemistry , Zakir Hussain College
(University of Delhi , J. L. Marg, New Delhi, 110002,
India
Published online: 22 Aug 2006.
To cite this article: R. K. Agarwal , Priyanka Garg , Himanshu Agarwal & Sulekh
Chandra (1997) Synthesis, Magneto-Spectral and Thermal Studies of Cobalt(II) and
Nickel(II) Complexes of 4-[N-(4-Dimethylaminobenzylidene) amino] Antipyrine,
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 27:2, 251-268, DOI:
10.1080/00945719708000150
To link to this article: http://dx.doi.org/10.1080/00945719708000150
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