Synlett p. 159 - 160 (1997)
Update date:2022-08-03
Topics:
Takatori, Kazuhiko
Tanaka, Kenji
Matsuoka, Katsunori
Morishita, Kazuyoshi
Kajiwara, Masahiro
An enantioselective synthesis of (-)-nonactic acid (2a) and (+)-8-epi-nonactic acid (2b) is described. The microbial reduction of the dl-ketone 3 with baker's yeast gave two easily separable diastereomeric alcohols 11a and 11b, each in over 97% ee. These alcohols were converted to 2a and 2b in 4 steps.
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Doi:10.1021/jo01106a019
(1958)Doi:10.1039/a605791h
(1997)Doi:10.1080/00945719708000196
(1997)Doi:10.1016/S0040-4039(97)00165-2
(1997)Doi:10.1246/bcsj.70.615
(1997)Doi:10.3987/com-96-7679
(1997)