Addition de Carbanions α Benchrotreniques sur Divers Aldehydes non Enolisables; Evolution des Produits Primaires d'Addition par Oxidation d'Oppenauer-Woodward, influence de la Substitution

DOI: 10.1016/0022-328X(87)80307-8

Source and publish data:

Journal of Organometallic Chemistry p. 353 - 364 (1987)

Update date:2022-09-26

Topics:

Authors:

Senechal-Tocquer, M. C.

Senechal, D.

Bihan, J. Y. Le

Gentric, D.

Caro, B.

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Article abstract of DOI:10.1016/0022-328X(87)80307-8

Aromatic hydrocarbons complexed with a Cr(CO)3 unit react with benzaldehydes and furfural in THF and in presence of t-BuOK at the benzylic position to give condensation products in good yields.Formation of ketones by in situ Oppenauer-Woodward oxidation is observed.Influence of ring substituents on this formation is discussed.

Full text of DOI:10.1016/0022-328X(87)80307-8

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