Sterically constrained tricyclic 2-oxazolidinone as excellent chiral auxiliary

DOI: 10.1016/S0040-4039(96)02402-1

Source and publish data:

Tetrahedron Letters p. 559 - 562 (1997)

Update date:2022-08-03

Topics:

Authors:

Nakamura, Taiju

Hashimoto, Noriaki

Ishizuka, Tadao

Kunieda, Takehisa

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Article abstract of DOI:10.1016/S0040-4039(96)02402-1

A new class of conformationally rigid 2-oxazolidinones with effectively bulky substituents, derived from the [4+2] cycloadduct of cyclopentadiene and a-oxazolone, serve as extremely powerful chiral auxiliaries for asymmetric alkylations, Diels-Alder reactions and conjugate addition reactions.

Full text of DOI:10.1016/S0040-4039(96)02402-1

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