1,4-asymmetric induction in palladium(II)-catalyzed intramolecular N-alkylation reaction. Construction of 2-functionalized 5-hydroxypiperidine

DOI: 10.1246/cl.1997.221

Source and publish data:

Chemistry Letters p. 221 - 222 (1997)

Update date:2022-08-03

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Authors:

Hirai, Yoshiro

Shibuya, Kaori

Fukuda, Yoko

Yokoyama, Hajime

Yamaguchi, Seiji

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Article abstract of DOI:10.1246/cl.1997.221

Palladium(II)-catalyzed cyclization of optically active urethanes containing an allylic alcohol moiety was examined. Efficient 1,4-asymmetric induction was found in this reaction. The cycloadducts were converted to pseudoconhydrine.

Full text of DOI:10.1246/cl.1997.221

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Product name:(2R,5R)-5-Benzoyloxy-2-propyl-piperidine-1-carboxylic acid tert-butyl ester

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