"Syn-Effect" in the Desulfonylation Reaction of α,α-Dialkylated (E)-Allylic Sulfones

DOI: 10.1246/bcsj.70.381

Source and publish data:

Bulletin of the Chemical Society of Japan p. 381 - 396 (1997)

Update date:2022-08-05

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Authors:

Shibayama, Atsushi

Nakamura, Tetsuya

Asada, Takahiro

Shintani, Takehiko

Ukaji, Yutaka

Kinoshita, Hideki

Inomata, Katsuhiko

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Article abstract of DOI:10.1246/bcsj.70.381

It was found that the desulfonylation reaction of α,α-dialkylated (E)-allylic sulfones with a base preferentially affords the sterically unfavorable (Z)-alkadienes. The relative degree of the "syn-effect", which is herein defined as an effect which stabil

Full text of DOI:10.1246/bcsj.70.381

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