Bulletin of the Chemical Society of Japan p. 381 - 396 (1997)
Update date:2022-08-05
Topics:
Shibayama, Atsushi
Nakamura, Tetsuya
Asada, Takahiro
Shintani, Takehiko
Ukaji, Yutaka
Kinoshita, Hideki
Inomata, Katsuhiko
It was found that the desulfonylation reaction of α,α-dialkylated (E)-allylic sulfones with a base preferentially affords the sterically unfavorable (Z)-alkadienes. The relative degree of the "syn-effect", which is herein defined as an effect which stabil
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