Tetrahedron Asymmetry p. 801 - 810 (1997)
Update date:2022-07-30
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Solladie, Guy
Somny, Frederic
Colobert, Francoise
The first enantioselective synthesis of (-)-(R)-haminol-1 is described in this paper. The chiral part of the molecule was prepared by reduction of an optically active β-ketosulfoxide. The all-trans trienic part was stereoselectively synthesized via reductive elimination of a 1,6-dibenzoate-2,4-diene with sodium amalgam.
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