
Tetrahedron p. 3577 - 3586 (1997)
Update date:2022-07-29
Topics:
Oppolzer, Wolfgang
Stammen, Blanda
The palladium-calalysed 'metallo-ene' step in a cyclisation/β-elimination reaction sequence has been shown to be suprafacial with respect to the olefinic component. This reaction has been applied to the synthesis of a trisubstituted exocyclic alkenyl pyrrolidine with complete stereocontrol.
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(1997)