Dehydration of α-silylalcohols in the reductive conversion of esters and ketones into alkenes

DOI: 10.1016/S0040-4039(97)00355-9

Source and publish data:

Tetrahedron Letters p. 2381 - 2382 (1997)

Update date:2022-07-30

Topics:

Authors:

Chenede, Alain

Abd.Rahman, Noorsaadah

Fleming, Ian

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(97)00355-9

The conversion of esters and ketones into easily dehydrated α-silylated alcohols, and protodesilylation of the resultant vinylsilanes, gives alkenes under relatively mild acidic conditions.

Full text of DOI:10.1016/S0040-4039(97)00355-9

Products guided by the article

Product name:1,1-Bis-(dimethyl-phenyl-silanyl)-5-phenyl-pentan-1-ol

Cas No:189251-09-0

R&D Labs maybe for 189251-09-0

APOLLO HEALTHCARE RESOURCES

Contact:+65 9658 0999

Address:26 Sin Ming Lane, Midview City, #05-118, Singapore 573971
Shanghai Hanshare Industry Co.,Ltd.

Contact:86 21 20960688

Address:RM902-903,Building E, Wanda Plaza,No.26,Zhoukang Road, Pudong District, Shanghai, China
NOVASYNCS CO., LTD

Contact:0512-63006287

Address:no.88.YISHENG Road,etdz-WUJIANG,SUZHOU,CHINA
Zhejiang Quzhou Zhengbang Organosilicon Co.,ltd.

Contact:86-570-3375195

Address:No.17 Lingqing Road technology industry,Quzhou City,Zhejiang Province,China
Ji'nan Orgachem Pharmaceutical Co.,Ltd

Contact:+86-531-82687810

Address:Jinan

Relevant to this article

Regioregular Head-to-Tail Poly(4-alkylquinoline)s: Synthesis, Characterization, Self-Organization, Photophysics, and Electroluminescence of New n-Type Conjugated Polymers

Doi:10.1021/ma0348021
(2003)
Syntheses and ligand-binding studies of 1α- and 17α-aminoalkyl dihydrotestosterone derivatives to human sex hormone-binding globulin

Doi:10.1016/S0039-128X(03)00092-8
(2003)
Reactions of derivatives of 3-thiocyanatopropionic acid with amines (author's transl)

Doi:10.1002/ardp.19773100411
(1977)
Heterolytic CH activation and catalysis by an O-donor iridium-hydroxo complex

Doi:10.1021/om060657e
(2006)
Synthesis and catalytic activity of rhodium diene complexes bearing indenyl-type fullerene η⁵-ligand

Doi:10.1016/S0022-328X(03)00465-0
(2003)
Doi:10.1007/BF00573554
()

Article Doi