Angewandte Chemie - International Edition in English p. 645 - 647 (1997)
Update date:2022-08-04
Topics:
Dunn
Rosair
Thomas
Weller
Welch
After more than 30 years of speculation on the mechanism of the isomerization of icosahedral carboranes and their analogues, isolation of 1- provides the first clue. This intermediate has an unprecendented, dosed, nonicosahedral structure. [Mo] = [Mo(η3-C3H5)CO)2].
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