Isolation of a nonicosahedral intermediate in the isomerization of an icosahedral metallacarborane

DOI: 10.1002/anie.199706451

Source and publish data:

Angewandte Chemie - International Edition in English p. 645 - 647 (1997)

Update date:2022-08-04

Topics:

Authors:

Dunn Dunn

Rosair Rosair

Thomas Thomas

Weller Weller

Welch Welch

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Article abstract of DOI:10.1002/anie.199706451

After more than 30 years of speculation on the mechanism of the isomerization of icosahedral carboranes and their analogues, isolation of 1^- provides the first clue. This intermediate has an unprecendented, dosed, nonicosahedral structure. [Mo] = [Mo(η³-C³H₅)CO)₂].

Full text of DOI:10.1002/anie.199706451

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Product name:N(C₂H₅)4⁽¹⁺⁾*(CO)2(C₃H₅)MoC₂B₉H₉(C₆H₅)2^(1-)=[N(C₂H₅)4][(CO)2(C₃H₅)MoC₂B₉H₉(C₆H₅)2]

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