Isolation of a nonicosahedral intermediate in the isomerization of an icosahedral metallacarborane

DOI: 10.1002/anie.199706451

Source and publish data:

Angewandte Chemie - International Edition in English p. 645 - 647 (1997)

Update date:2022-08-04

Topics:

Authors:

Dunn Dunn

Rosair Rosair

Thomas Thomas

Weller Weller

Welch Welch

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/anie.199706451

After more than 30 years of speculation on the mechanism of the isomerization of icosahedral carboranes and their analogues, isolation of 1^- provides the first clue. This intermediate has an unprecendented, dosed, nonicosahedral structure. [Mo] = [Mo(η³-C³H₅)CO)₂].

Full text of DOI:10.1002/anie.199706451

Products guided by the article

Product name:N(C₂H₅)4⁽¹⁺⁾*(CO)2(C₃H₅)MoC₂B₉H₉(C₆H₅)2^(1-)=[N(C₂H₅)4][(CO)2(C₃H₅)MoC₂B₉H₉(C₆H₅)2]

Cas No:189502-85-0

R&D Labs maybe for 189502-85-0

Synochem Ingredients Corp., Ltd.

Contact:+86-512-5636 2180

Address:Zhangjiagang Free Trade Zone
Shenyang Mole pharmaceutical Technology Development Co.,Ltd

Contact:+86-24-31204918/13889278616

Address:No.44, wanliutang road, shenhe District of Shenyang
Hangzhou yi lu biont technology Co., LTD

Contact:+86-571-88152630

Address:Hangzhoushi HuafengRoad Yicheng3Building1001room.
LINAN HAIHUA CHEMICAL CO LTD

Contact:86-571-61063068

Address:LINAN
Xi'an Kaixiang Photoelectric Technology Co., Ltd

website:http://www.kxmaterials.com/

Contact:86-29-15991651477

Address:Building 6, Biopharmaceutical Industry R&D Cluster Base, No. 16, Caotang 4th Road, Caotang Science and Technology Industrial Base, High-tech Zone, Xi'an City, Shaanxi Province, China

Relevant to this article

Synthesis and NMR spectral assignments of indol-3-yl pyridines through one-pot multi-component reaction

Doi:10.1002/mrc.2616
(2010)
Zirconium alkyl complexes supported by ureate ligands: Synthesis, characterization, and precursors to metal-element multiple bonds

Doi:10.1021/om100381d
(2010)
Novel trivalent anti-influenza reagent

Doi:10.1016/j.bmcl.2010.04.060
(2010)
Substituted 2-(3′,4′,5′-trimethoxybenzoyl)-benzo[b] thiophene derivatives as potent tubulin polymerization inhibitors

Doi:10.1016/j.bmc.2010.05.068
(2010)
A general approach to the synthesis of β²-amino acid derivatives via highly efficient catalytic asymmetric hydrogenation of α-aminomethylacrylates

Doi:10.1002/adsc.201000122
(2010)
Antitumor agents 278. 4-Amino-2H-benzo[h]chromen-2-one (ABO) analogs as potent in vitro anti-cancer agents

Doi:10.1016/j.bmcl.2010.05.079
(2010)

Article Doi