Asymmetric hetero Diels-Alder reaction of N-benzylimines derived from R-glyceraldehyde: A new approach to homochiral piperidine building blocks and its application to the synthesis of (2R)-4-oxopipecolic acid

DOI: 10.1016/S0040-4039(97)00397-3

Source and publish data:

Tetrahedron Letters p. 2547 - 2550 (1997)

Update date:2022-08-03

Topics:

Authors:

Badorrey, Ramon

Cativiela, Carlos

Diaz-De-Villegas, Maria D.

Galvez, Jose A.

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Article abstract of DOI:10.1016/S0040-4039(97)00397-3

The N-Benzyl imine derived from 2,3-di-O-benzyl-D-glyceraldehyde reacts with Danishefsky's diene to afford the corresponding hetero Diels-Alder adduct with a high diastereoselectivity. This compound can be transformed to enantiomerically pure (2R)-4-oxopi

Full text of DOI:10.1016/S0040-4039(97)00397-3

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Product name:4(1H)-Pyridinone, 2-[(1S)-1,2-bis(phenylmethoxy)ethyl]-2,3-dihydro-1-(phenylmethyl)-, (2R)-

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