Synthesis and Second-order Nonlinear Optical Properties of New Bipyridyl Metal Complexes

DOI: 10.1039/c39930001623

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1623 - 1624 (1993)

Update date:2022-08-03

Topics:

Authors:

Bourgault, M.

Mountassir, C.

Bozec, H. Le

Ledoux, I.

Pucetti, G.

Zyss, J.

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Article abstract of DOI:10.1039/c39930001623

The synthesis and characterisation of a series of new ?-donor substituted vinyl bipyridines and their rhenium, zinc and mercury complexes ; (η⁵-C5H5)Fe(η⁵-C5H4-)> with large nonlinear optical properties are presented; EFISH experiments at 1.34 μm show that complexation leads to a strong enhancement (by a factor of 3 to 9) of the molecular hyperpolarisability β(0).

Full text of DOI:10.1039/c39930001623

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