Synthetic studies of microsclerodermins. A stereoselective synthesis of a core building block for (2S,3R,4S,5S,6S,11E)-3-Amino-6-methyl-12- (4-methoxyphenyl)-2,4,5-trihydroxydodec-11-enoic acid (AMMTD)

DOI: 10.1016/S0040-4039(97)00522-4

Source and publish data:

Tetrahedron Letters p. 3013 - 3016 (1997)

Update date:2022-08-03

Topics:

Authors:

Sasaki, Shigekazu

Hamada, Yasumasa

Shioiri, Takayuki

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Article abstract of DOI:10.1016/S0040-4039(97)00522-4

A core building block 3 for (2S,3R,4S,5S,6S,11E)-3-amino-6-methyl-12- (4-methoxyphenyl)-2,4,5-trihydroxydodec-11-enoic acid (2, AMMTD) has been efficiently synthesized using the Sharpless asymmetric dihydroxylation and the Dondoni's furan addition to a ni

Full text of DOI:10.1016/S0040-4039(97)00522-4

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Product name:(E)-(S)-6-(tert-Butyl-diphenyl-silanyloxy)-5-methyl-hex-3-en-1-ol

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