Clemizole tetrachlorocuprate(II) and clemizole tetrachlorocobaltate(II)

DOI: 10.1107/S0108270196015922

Source and publish data:

Acta Crystallographica, Section C: Crystal Structure Communications p. 675 - 677 (1997)

Update date:2022-08-03

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Authors:

Parvez, Masood

Sabir, Aaliya P.

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Article abstract of DOI:10.1107/S0108270196015922

The crystal structures of 3-[4-(chlorophenyl)methyl]-2-(1-pyrrolidiniomethyl)-1H-benzimidazolium tetrachlorocopper(II), (C₁₉H₂₂ClN₃)[CuCl₄], and 3-[4-(chlorophenyl)methyl]-2-(1-pyrrolidiniomethyl)-1H-benzimidazolium tetrachlorocobalt(II), (C₁₉H₂₂ClN₃)[CoCl₄], show different conformations of the free radical dihydro cations of clemizole, a potent anti-allergic agent. The anions, CuCl₄^2- and CoCl₄^2-, exhibit flattened and normal tetrahedral geometries, respectively.

Full text of DOI:10.1107/S0108270196015922

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