Hydrogen atom abstraction from hexamethyl(Dewar benzene), hexamethylprismane, and a 1,3-hydrogen-shifted isomer of hexamethylbenzvalene. A study by electron paramagnetic resonance spectroscopy

DOI: 10.1021/jo00314a020

Source and publish data:

Journal of Organic Chemistry p. 96 - 98 (1981)

Update date:2022-08-03

Topics:

Authors:

Effio, A. A.

Ingold, K. U.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00314a020

Photochemically generated tert-butoxyls abstract an allylic hydrogen atom from hexamethyl(Dewar benzene).The resultant allylic radical 4, a^H(2 H) = 12.40 G, a^H(3 H) = 15.48 G> can be observed from 150 to 375 K.T

Full text of DOI:10.1021/jo00314a020

Products guided by the article

Product name:pentamethylbenzyl radical

Cas No:19121-64-3

R&D Labs maybe for 19121-64-3

Wuhan Chemwish Technology Co., Ltd

website:http://www.chemwish.com/

Contact:+86-27-67849912

Address:Room 1311, Unit 2, Block1, Innovation Road East Lake High-tech Development Zone Wuhan, Hubei，P.R. China
Shandong Dayi Chemical Co., Ltd.

website:http://www.dayi.com.cn

Contact:+86- 535-7388728. 15306386031

Address:No 1 Danya west road, Laiyang City, Shandong province
Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

website:http://www.bjgreenchem.com/

Contact:+86-427-6515887

Address:301,302, 3rd Floor, Building C-7, Dongsheng Science Park, Northern Territory, Zhongguancun, No. 66, Xixiaokou Road, Haidian District, Beijing
Shenyang Mole pharmaceutical Technology Development Co.,Ltd

Contact:+86-24-31204918/13889278616

Address:No.44, wanliutang road, shenhe District of Shenyang
Richest Group Ltd.

Contact:+86 21 5017 5386

Address:No 999,Jiangyue Rd, Minhang Dist ,201114,Shanghai ,China

Relevant to this article

Controlled Exchange of Achiral Linkers with Chiral Linkers in Zr-Based UiO-68 Metal-Organic Framework

Doi:10.1021/jacs.8b09606
(2018)
Synthesis of Conformationally-Constrained Glutamate Analogues of the Antitumor Agents DDATHF, LY254155, and LY231514

Doi:10.1021/jo9703459
(1997)
Synthesis of the naphthoic acid component of kedarcidin chromophore by routes employing photochemical and thermal electrocyclic ring closure reactions.

Doi:10.1016/S0040-4039(97)00844-7
(1997)
Reaction of 9-(β-D-Ribofuranosyl)purine with Alkalies: Kinetics and Mechanism

Doi:10.1021/jo00199a041
(1984)
Applications of Sugar Nitrones in Synthesis: The Total Synthesis of (+)-Polyoxin J

Doi:10.1021/jo9702913
(1997)
The first alkyl(silyl)palladium complexes: Formation by oxidative addition of silacyclobutanes to palladium complexes, reductive elimination, and other reactivities relevant to catalysis

Doi:10.1021/om970186j
(1997)

Article Doi