Hydrogen atom abstraction from hexamethyl(Dewar benzene), hexamethylprismane, and a 1,3-hydrogen-shifted isomer of hexamethylbenzvalene. A study by electron paramagnetic resonance spectroscopy

DOI: 10.1021/jo00314a020

Source and publish data:

Journal of Organic Chemistry p. 96 - 98 (1981)

Update date:2022-08-03

Topics:

Authors:

Effio, A. A.

Ingold, K. U.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00314a020

Photochemically generated tert-butoxyls abstract an allylic hydrogen atom from hexamethyl(Dewar benzene).The resultant allylic radical 4, a^H(2 H) = 12.40 G, a^H(3 H) = 15.48 G> can be observed from 150 to 375 K.T

Full text of DOI:10.1021/jo00314a020

Products guided by the article

Product name:pentamethylbenzyl radical

Cas No:19121-64-3

R&D Labs maybe for 19121-64-3

A.M FOOD CHEMICAL CO., LIMITED

Contact:86-531-87100375

Address:20Floor，Bblock，1Building，pharma-valley，Jinan，China
Shanghai Mintchem Development ., Ltd

Contact:0086 21 5190 8570

Address:R602,4#,89Nong, Mudan Road Pudong Shanghai China
Shanghai better-in Medical Technology Co.,LTD.

Contact:+86-21-38921049

Address:Lane 720 zhangjianggaoke cailun road, Pudong, Shanghai, room 513
Shanxi Sanwei Group Co.,Ltd

Contact:0086-357-6662688

Address:Zhaocheng town, Hongtong County, Linfen City, Shanxi Province
Lanzhou SchiffChem Co.,Ltd

Contact:86-931-8272767

Address:Room 602, No.461, Nanchang Road, Chengguan District, Lanzhou City, China PRC

Relevant to this article

Controlled Exchange of Achiral Linkers with Chiral Linkers in Zr-Based UiO-68 Metal-Organic Framework

Doi:10.1021/jacs.8b09606
(2018)
Synthesis of Conformationally-Constrained Glutamate Analogues of the Antitumor Agents DDATHF, LY254155, and LY231514

Doi:10.1021/jo9703459
(1997)
Synthesis of the naphthoic acid component of kedarcidin chromophore by routes employing photochemical and thermal electrocyclic ring closure reactions.

Doi:10.1016/S0040-4039(97)00844-7
(1997)
Reaction of 9-(β-D-Ribofuranosyl)purine with Alkalies: Kinetics and Mechanism

Doi:10.1021/jo00199a041
(1984)
Applications of Sugar Nitrones in Synthesis: The Total Synthesis of (+)-Polyoxin J

Doi:10.1021/jo9702913
(1997)
The first alkyl(silyl)palladium complexes: Formation by oxidative addition of silacyclobutanes to palladium complexes, reductive elimination, and other reactivities relevant to catalysis

Doi:10.1021/om970186j
(1997)

Article Doi