Hydrogen atom abstraction from hexamethyl(Dewar benzene), hexamethylprismane, and a 1,3-hydrogen-shifted isomer of hexamethylbenzvalene. A study by electron paramagnetic resonance spectroscopy

DOI: 10.1021/jo00314a020

Source and publish data:

Journal of Organic Chemistry p. 96 - 98 (1981)

Update date:2022-08-03

Topics:

Authors:

Effio, A. A.

Ingold, K. U.

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Article abstract of DOI:10.1021/jo00314a020

Photochemically generated tert-butoxyls abstract an allylic hydrogen atom from hexamethyl(Dewar benzene).The resultant allylic radical 4, a^H(2 H) = 12.40 G, a^H(3 H) = 15.48 G> can be observed from 150 to 375 K.T

Full text of DOI:10.1021/jo00314a020

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