A stereoselective synthesis of methyl β-C-lactoside through the tether approach

DOI: 10.1016/S0040-4039(98)00649-2

Source and publish data:

Tetrahedron Letters p. 3697 - 3700 (1998)

Update date:2022-08-04

Topics:

Authors:

Rubinstenn, Gilles

Mallet, Jean-Maurice

Sinay, Pierre

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Article abstract of DOI:10.1016/S0040-4039(98)00649-2

Methyl β-C-lactoside (β-D-Galp-C-(1→4)-β-Glcp-OMe) is stereoselectively synthesized by radical coupling of phenyl Se-β-D- galactopyranoside 5 onto exo-methylene-sugar 4, which are temporarily connected through a silaketal tether.

Full text of DOI:10.1016/S0040-4039(98)00649-2

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Product name:(2R,3R,4S,6S)-3-Benzyloxy-6-benzyloxymethyl-2-methoxy-5-methylene-tetrahydro-pyran-4-ol

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