The role of lithium 1,3-bis(trimethylsilyl)-1-aza-allyls in phosphorus chemistry

DOI: 10.1016/S0022-328X(96)06601-6

Source and publish data:

Journal of Organometallic Chemistry p. 243 - 255 (1997)

Update date:2022-08-04

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Authors:

Hitchcock, Peter B.

Lappert, Michael F.

Layh, Marcus

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Article abstract of DOI:10.1016/S0022-328X(96)06601-6

Treatment of the lithium 1-aza-allyl [Li{N(R)C(^tBu)CHR}]₂ 1, abbreviated as [Li(LL′)]₂, with PCl₃ gave in poor yields the trans-P,P′-dichlorodiazaphosphetidine ClPN(R′)P(C1)NR′ 3 (R = SiMe₃, R′ = C( View More

Full text of DOI:10.1016/S0022-328X(96)06601-6

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Product name:[(Z)-2-(1,1,1,3,3,3-Hexamethyl-disilazan-2-yl)-3,3-dimethyl-but-1-enyl]-diphenyl-phosphane

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