Tetrahedron p. 6365 - 6376 (1997)
Update date:2022-08-03
Topics:
Ponthieux, Sylvain
Outurquin, Francis
Paulmier, Claude
α-Phenylselanyl γ-unsaturated ketones were obtained through allylation of enolates generated by potassium t-butoxide cleavage of β-phenylselanyl silyl enol ethers derived from α-phenylselanyl ketones. With enoxysilanes prepared from α-phenylselanyl aldehydes, O-allylation and O-benzylation of the corresponding enolates were also observed.
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