
Synlett p. 469 - 470 (1997)
Update date:2022-08-03
Topics:
Danheiser, Rick L.
Lee, Thomas W.
Menichincheri, Maria
Brunelli, Steven
Nishiuchi, Masaki
An efficient two-step synthesis of alkylidenecyclopropanes is reported based on the addition of metallated cyclopropyl thiol esters to carbonyl compounds. Thermolysis of the resulting α-spirocyclopropyl-β-lactones at 105-150°C induces thermal [2+2] cycloreversion to furnish alkylidenecyclopropanes in good yield.
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Doi:10.1016/S0960-894X(97)00251-5
(1997)Doi:10.1007/BF00480619
()Doi:10.1016/S0040-4039(97)00918-0
(1997)Doi:10.1002/anie.199711121
(1997)Doi:10.1016/S0040-4020(97)00616-9
(1997)Doi:10.1016/S0040-4039(97)01062-9
(1997)