Radical reaction of the dimethacrylic ester of (2R,4R)-2,4-pentanediol. Addition-cyclization-termination process of high yield under rigorous stereocontrol of the termination step

DOI: 10.1016/S0040-4039(97)00699-0

Source and publish data:

Tetrahedron Letters p. 3547 - 3548 (1997)

Update date:2022-07-29

Topics:

Authors:

Sugimura, Takashi

Nagano, Shinya

Tai, Akira

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(97)00699-0

Photolysis of the dimethacrylic ester of (2R,4R)-2,4-pentanediol in the presence of thiophenol resulted in intramolecular C-C bond formation and, after desulfurization, diastereomerically pure (4S)-2,2,4-trimelhylglutarate ester was obtained in 93.6% for two steps.

Full text of DOI:10.1016/S0040-4039(97)00699-0

Products guided by the article

Product name:(2R,4R,9S)-2,4,7,7,9-Pentamethyl-[1,5]dioxecane-6,10-dione

Cas No:191486-39-2

R&D Labs maybe for 191486-39-2

Bayi Space LCD.

Contact:0086-010-69765588-8068

Address:Northern District yangfang Industry, Changping District, Beijing
Shanghai PengMo Biotechnology Co.,Ltd

website:http://www.pengmobio.lookchem.com

Contact:86-13052359378

Address:No.218 Hai Qu Road.Shanghai.China
Shandong Xinke Petrochemical Co., Ltd.

Contact:+86-546-7277016

Address:Gudao Industrial Park, Hekou District, Dongying, Shandong Province, China
Shijiazhuang Frontierchem Co., Ltd.

Contact:+86-311-89271196

Address:4-4-202 No.15 Biandian Street,Shijiazhuang
Wuxi Highness Chemical Co.,Ltd

website:https://www.phtpharmatech.com/

Contact:86-510-81771080

Address:No58 East Xinguan Rd, Guanlin Town, Yixing City, Jiangsu China

Relevant to this article

Doi:10.1039/j29680000277
(1968)
Synthesis and structural characterization of some novel metalloboroxides bearing boron-bound mesityl and fluoromesityl substituents: The molecular structure of the first metallaboroxane complex

Doi:10.1016/S0277-5387(96)00601-8
(1997)
A far-red emissive two-photon fluorescent probe for quantification of uracil in genomic DNA

Doi:10.1039/d1cc00016k
(2021)
Structure-activity relationship of cantharidin derivatives to protein phosphatases 1, 2A₁, and 2B

Doi:10.1016/S0960-894X(97)00316-8
(1997)
Ruthenium-catalyzed cyclocarbonylation of aliphatic amides through the regioselective activation of unactivated C(sp³)-H bonds

Doi:10.1016/j.tet.2013.02.006
(2013)
Flash vacuum pyrolysis of dialkyl diazobenzylphosphonates forming styrenes via a Wittig type intermediate

Doi:10.1016/S0040-4039(00)97806-7
(1990)

Article Doi