Synthesis and characterization of 1-amino-4-methylthio-2-nitro-1,3-butadienes

DOI: 10.1016/S0040-4020(97)00511-5

Source and publish data:

Tetrahedron p. 8531 - 8540 (1997)

Update date:2022-07-30

Topics:

Authors:

Surange, Sheetal S.

Kumaran, Govindaraj

Rajappa, Srinivasachari

Rajalakshmi

Pattabhi, Vasantha

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Article abstract of DOI:10.1016/S0040-4020(97)00511-5

Treatment of 3-nitrothiophene with prim, and sec. amines, followed by S-methylation leads to (Z,Z)-1- amino-4-methylthio-2-nitro-1,3-butadiene (3). Oxidation of these with LTA yields a mixture of the the 2-methylthio-4-nitropyrroles (6) and tile acetoxylated butadienes (8).

Full text of DOI:10.1016/S0040-4020(97)00511-5

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Product name:Cyclohexanamine, N-[4-(methylthio)-2-nitro-1,3-butadienyl]-, (Z,Z)-

Cas No:193144-25-1

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