Journal of Organometallic Chemistry p. 251 - 253 (1997)
Update date:2022-08-05
Topics:
Van Den Beuken, Ester
Samson, Sylvie
Sandoe, Elizabeth J.
Stephenson, G. Richard
The first example of an alkyne-substituted tricarbonyl(η5-cyclohexadienyl)iron(1+) complex has been prepared and the ω directing effect of the phenylethynyl substituent has been demonstrated in nucleophile addition reactions. Addition of NC- also occurs at the α position to form an unusual η1, η3-structure.
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